Photochemical Tyrosine Oxidation with a Hydrogen-Bonded Proton Acceptor by Bidirectional Proton-Coupled Electron Transfer

Amino acid radical generation and transport are fundamentally important to numerous essential biological processes to which small molecule models lend valuable mechanistic insights. Pyridyl-amino acid-methyl esters are appended to a rhenium(I) tricarbonyl 1,10-phenanthroline core to yield rhenium–am...

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Bibliographic Details
Main Authors: Pizano, Arturo A., Yang, Jay L., Nocera, Daniel G.
Format: Artigo
Language:Inglês
Published: 2012
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3594118/
https://ncbi.nlm.nih.gov/pubmed/23495362
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20113E
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