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Tuning the Proton‐Coupled Electron‐Transfer Rate by Ligand Modification in Catalyst–Dye Supramolecular Complexes for Photocatalytic Water Splitting

In view of the considerably high activation energy barrier of the O−O bond formation photocatalytic step in water oxidation, it is essential to understand if and how nonadiabatic factors can accelerate the proton‐coupled electron transfer (PCET) rate in this process to find rational design strategie...

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Publicado en:ChemSusChem
Main Authors: Yang, de Groot, Huub J. M., Buda, Francesco
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2020
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7821158/
https://ncbi.nlm.nih.gov/pubmed/32871047
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cssc.202001863
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