Formation of Nucleophilic Allylboranes from Molecular Hydrogen and Allenes Catalyzed by a Pyridonate Borane that Displays Frustrated Lewis Pair Reactivity

Here we report the in situ generation of nucleophilic allylboranes from H(2) and allenes mediated by a pyridonate borane that displays frustrated‐Lewis‐pair reactivity. Experimental and computational mechanistic investigations reveal that upon H(2) activation, the covalently bound pyridonate substit...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Angew Chem Int Ed Engl
Main Authors: Hasenbeck, Max, Ahles, Sebastian, Averdunk, Arthur, Becker, Jonathan, Gellrich, Urs
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2020
Teme:
Research Articles
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC7814673/
https://ncbi.nlm.nih.gov/pubmed/32926511
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011790
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