Formation of Nucleophilic Allylboranes from Molecular Hydrogen and Allenes Catalyzed by a Pyridonate Borane that Displays Frustrated Lewis Pair Reactivity

Here we report the in situ generation of nucleophilic allylboranes from H(2) and allenes mediated by a pyridonate borane that displays frustrated‐Lewis‐pair reactivity. Experimental and computational mechanistic investigations reveal that upon H(2) activation, the covalently bound pyridonate substit...

Celý popis

Uloženo v:
Podrobná bibliografie
Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Hasenbeck, Max, Ahles, Sebastian, Averdunk, Arthur, Becker, Jonathan, Gellrich, Urs
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2020
Témata:
Research Articles
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC7814673/
https://ncbi.nlm.nih.gov/pubmed/32926511
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011790
Tagy: Přidat tag
Žádné tagy, Buďte první, kdo otaguje tento záznam!

Podobné jednotky