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Efficient Organocatalytic Dehydrogenation of Ammonia Borane
Dehydrogenation of ammonia borane by sterically encumbered pyridones as organocatalysts is reported. With 6‐tert‐butyl‐2‐thiopyridone as the catalyst, a turnover frequency (TOF) of 88 h(−1) was achieved. Experimental mechanistic investigations, substantiated by DLPNO‐CCSD(T) computations, indicate a...
Tallennettuna:
| Julkaisussa: | Angew Chem Int Ed Engl |
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| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
John Wiley and Sons Inc.
2019
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7003781/ https://ncbi.nlm.nih.gov/pubmed/31573726 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201910636 |
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