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Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant metal complexes generate stabilized and unstabilized carbon-centered radicals from alkenes of various substitution patterns with rob...

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Foilsithe in:Chem Sci
Main Authors: Shevick, Sophia L., Wilson, Conner V., Kotesova, Simona, Kim, Dongyoung, Holland, Patrick L., Shenvi, Ryan A.
Formáid: Artigo
Teanga:Inglês
Foilsithe: Royal Society of Chemistry 2020
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7810138/
https://ncbi.nlm.nih.gov/pubmed/33520153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04112b
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