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The Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study

A growing and useful class of alkene coupling reactions involve hydrogen atom transfer (HAT) from a metal-hydride species to an alkene to form a free radical, which is responsible for subsequent bond formation. Here, we use a combination of experimental and computational investigations to map out th...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Kim, Dongyoung, Rahaman, S. M. Wahidur, Mercado, Brandon Q., Poli, Rinaldo, Holland, Patrick L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6953484/
https://ncbi.nlm.nih.gov/pubmed/31025567
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02117
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