Synchrotron X-radiolysis of l-cysteine at the sulfur K-edge: Sulfurous products, experimental surprises, and dioxygen as an oxidoreductant

In situ inventory of sulfurous products from the sulfur K-edge synchrotron X-radiolysis of l-cysteine in solid-phase and anaerobic (pH 5) and air-saturated (pH 5, 7, and 9) solutions without and with 40% glycerol is reported. Sequential K-edge X-ray Absorption Spectroscopic (XAS) spectra were acquir...

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Veröffentlicht in:J Chem Phys
Hauptverfasser: Frank, Patrick, Sarangi, Ritimukta, Hedman, Britt, Hodgson, Keith O.
Format: Artigo
Sprache:Inglês
Veröffentlicht: AIP Publishing LLC 2019
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7791807/
https://ncbi.nlm.nih.gov/pubmed/30876351
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.5079419
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