Učitavanje...
Spin-Polarization Induced Pre-edge Transitions in the Sulfur K-edge XAS Spectra of Open-Shell Transition-Metal Sulfates: Spectroscopic Validation of σ-Bond Electron Transfer
Sulfur K-edge XAS spectra of the monodentate sulfate complexes [M(II)(itao)(SO(4))(H(2)O)(0,1)] and [Cu(Me(6)tren)(SO(4))] exhibit well-defined pre-edge transitions at 2479.4 eV, 2479.9 eV, 2478.4 eV, and 2477.7 eV, respectively (M = Co, Ni, Cu), despite having no direct metal-sulfur bond, while the...
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| Izdano u: | Inorg Chem |
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| Glavni autori: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2017
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5733802/ https://ncbi.nlm.nih.gov/pubmed/28068071 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b00991 |
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