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Electron Redistribution within the Nitrogenase Active Site FeMo-Cofactor During Reductive Elimination of H(2) to Achieve N≡N Triple-Bond Activation
Nitrogen fixation by nitrogenase begins with the accumulation of four reducing equivalents at the active-site FeMo-cofactor (FeMo-co), generating a state (denoted E(4)(4H)) with two [Fe─H─Fe] bridging hydrides. Recently, photolytic reductive elimination (re) of the E(4)(4H) hydrides showed that enzy...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7783777/ https://ncbi.nlm.nih.gov/pubmed/33326225 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c07914 |
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