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Michael addition with an olefinic pyridine: organometallic nucleophiles and carbon electrophiles.
The conjugate addition reactions of trans-1,2-di-(2-pyridyl)ethylene have been studied. This substrate reacts with organolithium nucleophiles and the resulting anionic intermediates may be trapped by proton or various carbonyl-based electrophiles. It is suggested that the dipyridyl structure stabili...
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| Published in: | J Org Chem |
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| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7781395/ https://ncbi.nlm.nih.gov/pubmed/32883082 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00823 |
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