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Isolable Silicon‐Based Polycations with Lewis Superacidity
Molecular silicon polycations of the types R(2)Si(2+) and RSi(3+) (R=H, organic groups) are elusive Lewis superacids and currently unknown in the condensed phase. Here, we report the synthesis of a series of isolable terpyridine‐stabilized R(2)Si(2+) and RSi(3+) complexes, [R(2)Si(terpy)](2+) (R=Ph...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756528/ https://ncbi.nlm.nih.gov/pubmed/32935903 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011696 |
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