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Isolable Silicon‐Based Polycations with Lewis Superacidity

Molecular silicon polycations of the types R(2)Si(2+) and RSi(3+) (R=H, organic groups) are elusive Lewis superacids and currently unknown in the condensed phase. Here, we report the synthesis of a series of isolable terpyridine‐stabilized R(2)Si(2+) and RSi(3+) complexes, [R(2)Si(terpy)](2+) (R=Ph...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Hermannsdorfer, André, Driess, Matthias
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2020
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756528/
https://ncbi.nlm.nih.gov/pubmed/32935903
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202011696
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