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A Chatt‐Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia
With [Mo(N(2))(P(2) (Me)PP(2) (Ph))] the first Chatt‐type complex with one coordination site catalytically converting N(2) to ammonia is presented. Employing SmI(2) as reductant and H(2)O as proton source 26 equivalents of ammonia are generated. Analogous Mo(0)‐N(2) complexes supported by a combinat...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756349/ https://ncbi.nlm.nih.gov/pubmed/32815654 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202003549 |
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