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Synthesis of DiamidoPyrrolyl Molybdenum Complexes Relevant to Reduction of Dinitrogen to Ammonia

A potentially useful trianionic ligand for the reduction of dinitrogen catalytically by molybdenum complexes is one in which one of the arms in a [(RNCH(2)CH(2))(3)N](3−) ligand is replaced by a 2-mesitylpyrrolyl-α-methyl arm, i.e., [(RNCH(2)CH(2))(2)NCH(2)(2-MesitylPyrrolyl)](3−) (R = C(6)F(5), 3,5...

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Detalhes bibliográficos
Main Authors: Chin, J. M., Schrock, R. R., Müller, P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2931342/
https://ncbi.nlm.nih.gov/pubmed/20799738
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic100856n
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