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Conformation and Aromaticity Switching in a Curved Non‐Alternant sp(2) Carbon Scaffold

A curved sp(2) carbon scaffold containing fused pentagon and heptagon units (1) was synthesized by Pd‐catalyzed [5+2] annulation from a 3,9‐diboraperylene precursor and shows two reversible oxidation processes at low redox potential, accompanied by a butterfly‐like motion. Stepwise oxidation produce...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Zhu, Chongwei, Shoyama, Kazutaka, Würthner, Frank
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756343/
https://ncbi.nlm.nih.gov/pubmed/32815658
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010077
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