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Conformation and Aromaticity Switching in a Curved Non‐Alternant sp(2) Carbon Scaffold
A curved sp(2) carbon scaffold containing fused pentagon and heptagon units (1) was synthesized by Pd‐catalyzed [5+2] annulation from a 3,9‐diboraperylene precursor and shows two reversible oxidation processes at low redox potential, accompanied by a butterfly‐like motion. Stepwise oxidation produce...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7756343/ https://ncbi.nlm.nih.gov/pubmed/32815658 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010077 |
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