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Silver-catalyzed synthesis of β-fluorovinylphosphonates by phosphonofluorination of aromatic alkynes

A silver-catalyzed three-component reaction involving alkynes, Selectfluor(®), and diethyl phosphite was employed for the one-pot formation of C(sp(2))–F and C(sp(2))–P bonds to provide an efficient access to β-fluorovinylphosphonates in a highly regio- and stereoselective manner under mild reaction...

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Veröffentlicht in:Beilstein J Org Chem
Hauptverfasser: Zhang, Yajing, Tian, Qingshan, Zhang, Guozhu, Zhang, Dayong
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2020
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7753110/
https://ncbi.nlm.nih.gov/pubmed/33414856
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.258
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