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Silver‐Catalyzed Stereoselective Aminosulfonylation of Alkynes
A silver‐catalyzed intermolecular aminosulfonylation of terminal alkynes with sodium sulfinates and TMSN(3) is reported. This three‐component reaction proceeds through sequential hydroazidation of the terminal alkyne and addition of a sulfonyl radical to the resultant vinyl azide. The method enables...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5655761/ https://ncbi.nlm.nih.gov/pubmed/28627090 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705122 |
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