Silver‐Catalyzed Stereoselective Aminosulfonylation of Alkynes

A silver‐catalyzed intermolecular aminosulfonylation of terminal alkynes with sodium sulfinates and TMSN(3) is reported. This three‐component reaction proceeds through sequential hydroazidation of the terminal alkyne and addition of a sulfonyl radical to the resultant vinyl azide. The method enables...

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Spremljeno u:
Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Ning, Yongquan, Ji, Qinghe, Liao, Peiqiu, Anderson, Edward A., Bi, Xihe
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2017
Teme:
Communications
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5655761/
https://ncbi.nlm.nih.gov/pubmed/28627090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705122
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