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Synthesis of fluoranthenes by hydroarylation of alkynes catalyzed by gold(I) or gallium trichloride

Electrophilic gold(I) catalyst 6 competes with GaCl(3) as the catalyst of choice in the synthesis of fluoranthenes by intramolecular hydroarylation of alkynes. The potential of this catalyst for the preparation of polyarenes is illustrated by a synthesis of two functionalized decacyclenes in a one-p...

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Detalhes bibliográficos
Main Authors: Pascual, Sergio, Bour, Christophe, de Mendoza, Paula, Echavarren, Antonio M
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3252853/
https://ncbi.nlm.nih.gov/pubmed/22238527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.178
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