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Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes

We report the first example of enantioselective, intermolecular diarylcarbene insertion into Si–H bonds for synthesis of silicon-stereogenic silanes. Dirhodium(II) carboxylates catalyze an Si–H insertion using carbenes derived from diazo compounds where selective formation of an enantioenriched sili...

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發表在:J Am Chem Soc
Main Authors: Jagannathan, Jake R., Fettinger, James C., Shaw, Jared T., Franz, Annaliese K.
格式: Artigo
語言:Inglês
出版: 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7747653/
https://ncbi.nlm.nih.gov/pubmed/32539370
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04533
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