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The Silicon–Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes

[Image: see text] The use of chiral enol silanes in fundamental transformations such as Mukaiyama aldol, Michael, and Mannich reactions as well as Saegusa–Ito dehydrogenations has enabled the chemical synthesis of enantiopure natural products and valuable pharmaceuticals. However, accessing these in...

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書目詳細資料
發表在:J Am Chem Soc
Main Authors: Zhou, Hui, Bae, Han Yong, Leutzsch, Markus, Kennemur, Jennifer L., Bécart, Diane, List, Benjamin
格式: Artigo
語言:Inglês
出版: American Chemical Society 2020
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7426905/
https://ncbi.nlm.nih.gov/pubmed/32786813
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c06677
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