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The Silicon–Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes

[Image: see text] The use of chiral enol silanes in fundamental transformations such as Mukaiyama aldol, Michael, and Mannich reactions as well as Saegusa–Ito dehydrogenations has enabled the chemical synthesis of enantiopure natural products and valuable pharmaceuticals. However, accessing these in...

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Publicat a:J Am Chem Soc
Autors principals: Zhou, Hui, Bae, Han Yong, Leutzsch, Markus, Kennemur, Jennifer L., Bécart, Diane, List, Benjamin
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2020
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7426905/
https://ncbi.nlm.nih.gov/pubmed/32786813
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c06677
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