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The Silicon–Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes

[Image: see text] The use of chiral enol silanes in fundamental transformations such as Mukaiyama aldol, Michael, and Mannich reactions as well as Saegusa–Ito dehydrogenations has enabled the chemical synthesis of enantiopure natural products and valuable pharmaceuticals. However, accessing these in...

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Pubblicato in:J Am Chem Soc
Autori principali: Zhou, Hui, Bae, Han Yong, Leutzsch, Markus, Kennemur, Jennifer L., Bécart, Diane, List, Benjamin
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2020
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7426905/
https://ncbi.nlm.nih.gov/pubmed/32786813
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c06677
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