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Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes
We report the first example of enantioselective, intermolecular diarylcarbene insertion into Si–H bonds for synthesis of silicon-stereogenic silanes. Dirhodium(II) carboxylates catalyze an Si–H insertion using carbenes derived from diazo compounds where selective formation of an enantioenriched sili...
Shranjeno v:
| izdano v: | J Am Chem Soc |
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| Main Authors: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7747653/ https://ncbi.nlm.nih.gov/pubmed/32539370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04533 |
| Oznake: |
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