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Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes
We report the first example of enantioselective, intermolecular diarylcarbene insertion into Si–H bonds for synthesis of silicon-stereogenic silanes. Dirhodium(II) carboxylates catalyze an Si–H insertion using carbenes derived from diazo compounds where selective formation of an enantioenriched sili...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7747653/ https://ncbi.nlm.nih.gov/pubmed/32539370 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c04533 |
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