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Catalytic generation of alkoxy radicals from unfunctionalized alcohols
Alkoxy radicals have long been recognized as powerful synthetic intermediates with well-established reactivity patterns. Due to the high bond dissociation free energy of aliphatic alcohol O–H bonds, these radicals are difficult to access through direct homolysis, and conventional methods have instea...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7747465/ https://ncbi.nlm.nih.gov/pubmed/33384861 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04542j |
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