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Catalytic Carbocation Generation Enabled by the Mesolytic Cleavage of Alkoxyamine Radical Cations
We describe a new catalytic method for accessing carbocation intermediates via the mesolytic cleavage of alkoxyamine radical cations. In this process, electron transfer between an excited state oxidant and a TEMPO-derived alkoxyamine substrate gives rise to a radical cation with a remarkably weak C-...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5102159/ https://ncbi.nlm.nih.gov/pubmed/27403637 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201604619 |
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