Dinuclear Rhenium Complexes with a Bridging Helicene-bis-bipyridine Ligand: Synthesis, Structure, and Photophysical and Chiroptical Properties

By attaching pyridine groups to a diaza[6]helicene, a helical, bis-ditopic, bis-NN-coordinating ligand can be accessed. Dinuclear rhenium complexes featuring this bridging ligand, of the form [{Re(CO)(3)Cl}(2)(NN−NN)], have been prepared and resolved to give enantiopure complexes. These complexes ar...

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Publicado no:Chempluschem
Main Authors: Saleh, Nidal, Kundu, Debsouri, Vanthuyne, Nicolas, Olesiak-Banska, Joanna, Pniakowska, Anna, Matczyszyn, Katarzyna, Chang, Victoria Y., Muller, Gilles, Williams, J. A. Gareth, Srebro-Hooper, Monika, Autschbach, Jochen, Crassous, Jeanne
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7745256/
https://ncbi.nlm.nih.gov/pubmed/32965092
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cplu.202000559
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