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Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn(2+) binding
The molecular conformation of a bis-helicenic terpyridine system is strongly modified upon binding to Zn(II) ion, a process that is accompanied by large changes in the optical and chiroptical properties. This system affords a new type of helicene-based chiroptical switching.
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| Publicado no: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4840045/ https://ncbi.nlm.nih.gov/pubmed/27054507 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc01748g |
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