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Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn(2+) binding

The molecular conformation of a bis-helicenic terpyridine system is strongly modified upon binding to Zn(II) ion, a process that is accompanied by large changes in the optical and chiroptical properties. This system affords a new type of helicene-based chiroptical switching.

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Isla, Helena, Srebro-Hooper, Monika, Jean, Marion, Vanthuyne, Nicolas, Roisnel, Thierry, Lunkley, Jamie L., Muller, Gilles, Gareth Williams, J. A., Autschbach, Jochen, Crassous, Jeanne
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4840045/
https://ncbi.nlm.nih.gov/pubmed/27054507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cc01748g
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