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Synthesis and chiroptical properties of hexa-, octa- and deca-azaborahelicenes: influence of the helicene’s size and of the number of boron atoms

Four members of a new class of cycloborylated hexa- to deca-helicenes (1a–d) have been prepared in enantiopure forms, along with cycloplatinated deca-helicenes (1d′, 1d(1)) further extending a family of cycloplatinated hexa- to octa-helicenes reported previously. The azabora[n]helicenes display inte...

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Bibliografiske detaljer
Udgivet i:Chemistry
Main Authors: Shen, Chengshuo, Srebro-Hooper, Monika, Jean, Marion, Vanthuyne, Nicolas, Toupet, Loïc, Gareth Williams, J. A., Torres, Alexis R., Riives, Adrian J., Muller, Gilles, Autschbach, Jochen, Crassous, Jeanne
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5388065/
https://ncbi.nlm.nih.gov/pubmed/27754565
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201604398
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