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Formation of Monofluorinated Radical Cofactor in Galactose Oxidase through Copper-Mediated C−F Bond Scission
Galactose oxidase (GAO) contains a Cu(II)-ligand radical cofactor. The cofactor, which is autocatalytically generated through the oxidation of the copper, consists of a cysteine-tyrosine radical (Cys-Tyr(•)) as a copper ligand. The formation of the crosslinked thioether bond is accompanied by a C-H...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2020
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7737484/ https://ncbi.nlm.nih.gov/pubmed/33091303 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c08992 |
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