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Sulfanyl stabilization of copper-bonded phenoxyls in model complexes and galactose oxidase
Integrating sulfanyl substituents into copper-bonded phenoxyls significantly alters their optical and redox properties and provides insight into the influence of cysteine modification of the tyrosine cofactor in the enzyme galactose oxidase. The model complexes [1(SR2)](+) are class II mixed-valent...
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| Main Authors: | , , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
National Academy of Sciences
2011
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3219126/ https://ncbi.nlm.nih.gov/pubmed/22065750 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1109931108 |
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