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Electrochemical and spectroscopic effects of mixed substituents in bis(phenolate)–copper(II) galactose oxidase model complexes
Non-symmetric substitution of salen (1(R1,R2)) and reduced salen (2(R1,R2)) Cu(II)-phenoxyl complexes with a combination of -(t)Bu, -S(i)Pr, and -OMe substituents leads to dramatic differences in their redox and spectroscopic properties, providing insight into the influence of the cysteine-modified...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3343640/ https://ncbi.nlm.nih.gov/pubmed/22471355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211247f |
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