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Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate
We report herein a practical method to generate CF(3)Se(−) (and R(F)Se(−)) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluoroalkylselenolations have also been described....
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| Publicat a: | Beilstein J Org Chem |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Beilstein-Institut
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7736694/ https://ncbi.nlm.nih.gov/pubmed/33363671 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.16.252 |
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