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Phosphine-Catalyzed β′-Umpolung Addition of Nucleophiles to Activated α-Alkyl Allenes

[Image: see text] Highly functionalized alkenes can be prepared through phosphine-catalyzed β′-umpolung additions of nucleophiles (carbon-, oxygen-, nitrogen-, and sulfur-centered) to activated α-disubstituted allenes, providing many potentially useful synthetic intermediates in good to excellent yi...

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Detalhes bibliográficos
Main Authors: Martin, Tioga J., Vakhshori, Venus G., Tran, Yang S., Kwon, Ohyun
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3094471/
https://ncbi.nlm.nih.gov/pubmed/21491870
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200697m
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