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Enantioconvergent Amination of Racemic Tertiary C–H Bonds

Racemization is considered to be an intrinsic stereochemical feature of free radical chemistry as can be seen in traditional radical halogenation reactions of optically active tertiary C–H bonds. If the facile process of radical racemization could be effectively combined with an ensuing step of bond...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lang, Kai, Li, Chaoqun, Kim, Isaac, Zhang, X. Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7725894/
https://ncbi.nlm.nih.gov/pubmed/33249845
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c11103
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