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Re(2)O(7)‑Catalyzed Approach to Spirocyclic Ether Formation from Acyclic Precursors: Observation of Remote Stereoinduction
Ketones that are flanked by an allylic alcohol and an alkene isomerize to spirocyclic ethers in the presence of Re(2)O(7) through allylic alcohol transposition, oxocarbenium ion formation, and Prins cyclization. These processes provide significant increases in molecular complexity, with multiple ste...
Tallennettuna:
| Julkaisussa: | Org Lett |
|---|---|
| Päätekijät: | , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2019
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7720882/ https://ncbi.nlm.nih.gov/pubmed/31247770 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01660 |
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