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Synthesis of Spirocyclic Ethers by Enantioselective Copper-Catalyzed Carboetherification of Alkenols

Spirocyclic ethers can be found in bioactive compounds. This copper-catalyzed enantioselective alkene carboetherification provides 5,5-, 5,6- and 6,6-spirocyclic products containing fully substituted chiral carbon centers with up to 99% enantiomeric excess. This reaction features the formation of tw...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Angew Chem Int Ed Engl
Prif Awduron: Karyakarte, Shuklendu D., Um, Chanchamnan, Berhane, Ilyas A., Chemler, Sherry R.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2018
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC6375082/
https://ncbi.nlm.nih.gov/pubmed/30117646
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808554
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