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Diarylmethane synthesis through Re(2)O(7)-catalyzed bimolecular dehydrative Friedel–Crafts reactions

This manuscript describes the application of Re(2)O(7) to the syntheses of diarylmethanes from benzylic alcohols through solvolysis followed by Friedel–Crafts alkylation. The reactions are characterized by broad substrate scope, low catalyst loadings, high chemical yields, and minimal waste generati...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Qin, Qi, Xie, Youwei, Floreancig, Paul E.
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2018
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6251338/
https://ncbi.nlm.nih.gov/pubmed/30568776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03570a
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