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Redox-Neutral TEMPO Catalysis Toward Direct Radical (Hetero)Aryl C–H Di- and Trifluoromethoxylation

Applications of TEMPO(•) catalysis for the development of redox-neutral transformations are rare. Herein, we report the first TEMPO(•)-catalyzed, redox-neutral C–H di- and trifluoromethoxylation of (hetero)arenes. The reaction exhibits a broad substrate scope, has high functional group tolerance, an...

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Dades bibliogràfiques
Publicat a:Angew Chem Int Ed Engl
Autors principals: Lee, Johnny W., Lim, Sanghyun, Maienshein, Daniel N., Liu, Peng, Ngai, Ming-Yu
Format: Artigo
Idioma:Inglês
Publicat: 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7720849/
https://ncbi.nlm.nih.gov/pubmed/32830430
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009490
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