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Redox-active Reagents for Photocatalytic Generation of the OCF3 Radical and (Hetero)Aryl C-H Trifluoromethoxylation

The trifluoromethoxy (OCF(3)) radical is of great importance in organic chemistry. Yet, catalytic and selective generation of this radical at room temperature and pressure remains a longstanding challenge. Herein, we report the design and development of a redox- active cationic reagent 1 that enable...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Zheng, Weijia, Lee, Johnny W., Morales-Rivera, Cristian A., Liu, Peng, Ngai, Ming-Yu
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6278930/
https://ncbi.nlm.nih.gov/pubmed/30238593
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808495
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