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Redox-active Reagents for Photocatalytic Generation of the OCF3 Radical and (Hetero)Aryl C-H Trifluoromethoxylation
The trifluoromethoxy (OCF(3)) radical is of great importance in organic chemistry. Yet, catalytic and selective generation of this radical at room temperature and pressure remains a longstanding challenge. Herein, we report the design and development of a redox- active cationic reagent 1 that enable...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6278930/ https://ncbi.nlm.nih.gov/pubmed/30238593 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201808495 |
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