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Redox-Neutral TEMPO Catalysis Toward Direct Radical (Hetero)Aryl C–H Di- and Trifluoromethoxylation
Applications of TEMPO(•) catalysis for the development of redox-neutral transformations are rare. Herein, we report the first TEMPO(•)-catalyzed, redox-neutral C–H di- and trifluoromethoxylation of (hetero)arenes. The reaction exhibits a broad substrate scope, has high functional group tolerance, an...
Shranjeno v:
| izdano v: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2020
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7720849/ https://ncbi.nlm.nih.gov/pubmed/32830430 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009490 |
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