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A Phosphanyl‐Phosphagallene that Functions as a Frustrated Lewis Pair
Phosphagallenes (1 a/1 b) featuring double bonds between phosphorus and gallium were synthesized by reaction of (phosphanyl)phosphaketenes with the gallium carbenoid Ga(Nacnac) (Nacnac=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)). The stability of these species is dependent on the saturation of the phosphany...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7693089/ https://ncbi.nlm.nih.gov/pubmed/32615007 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202008207 |
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