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A Phosphanyl‐Phosphagallene that Functions as a Frustrated Lewis Pair

Phosphagallenes (1 a/1 b) featuring double bonds between phosphorus and gallium were synthesized by reaction of (phosphanyl)phosphaketenes with the gallium carbenoid Ga(Nacnac) (Nacnac=HC[C(Me)N(2,6‐i‐Pr(2)C(6)H(3))](2)). The stability of these species is dependent on the saturation of the phosphany...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Wilson, Daniel W. N., Feld, Joey, Goicoechea, Jose M.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7693089/
https://ncbi.nlm.nih.gov/pubmed/32615007
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202008207
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