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C—N-Coupled Metabolites Yield Insights into Dynemicin A Biosynthesis
The biosynthesis of the three structural subclasses of enediyne antitumor antibiotics remains largely unknown beyond a common C(16)-hexaene precursor. For the anthraquinone-fused subtype, however, an unexpected iodoanthracene γ-thiolactone was established to be a mid-pathway intermediate to dynemici...
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| Publicado no: | Chembiochem |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7685002/ https://ncbi.nlm.nih.gov/pubmed/32198800 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.202000177 |
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