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Experimental and Theoretical Study on the “2,2′-Bipiridyl-Ni-Catalyzed” Hirao Reaction of >P(O)H Reagents and Halobenzenes: A Ni(0) → Ni(II) or a Ni(II) → Ni(IV) Mechanism?
[Image: see text] It was found by us that the P–C coupling reaction of >P(O)H reagents with PhX (X = I and Br) in the presence of NiCl(2)/Zn as the precursors for the assumed Ni(0) complexant together with 2,2′-bipyridine as the ligand took place only with PhI at 50/70 °C. M06-2X/6-31G(d,p)//PCM(...
Gardado en:
| Publicado en: | J Org Chem |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
American Chemical
Society
2020
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7684577/ https://ncbi.nlm.nih.gov/pubmed/32407093 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.0c00804 |
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