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New Developments on the Hirao Reactions, Especially from “Green” Point of View

BACKGROUND: The Hirao reaction discovered ca. 35 years ago is an important P–C coupling protocol between dialkyl phosphites and aryl halides in the presence of Pd(PPh3)4 as the catalyst and a base to provide aryl phosphonates. Then, the reaction was extended to other P-reagents, such as secondary ph...

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Bibliographic Details
Published in:Curr Org Synth
Main Authors: Henyecz, Réka, Keglevich, György
Format: Artigo
Language:Inglês
Published: Bentham Science Publishers 2019
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7432197/
https://ncbi.nlm.nih.gov/pubmed/31984929
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.2174/1570179416666190415110834
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