N–H Bond Formation at a Diiron Bridging Nitride

Despite their connection to ammonia synthesis, little is known about the ability of iron-bound, bridging nitrides to form N–H bonds. Herein we report a linear diiron bridging nitride complex supported by a redox-active macrocycle. The unique ability of the ligand scaffold to adapt to the geometric p...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Zhang, Shaoguang, Cui, Peng, Liu, Tianchang, Wang, Qiuran, Longo, Thomas J., Thierer, Laura M., Manor, Brian C., Gau, Michael R., Carroll, Patrick J., Papaefthymiou, Georgia C., Tomson, Neil C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2020
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7680347/
https://ncbi.nlm.nih.gov/pubmed/32441448
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006391
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