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Pyridyldiimine macrocyclic ligands: Influences of template ion, linker length and imine substitution on ligand synthesis, structure and redox properties

A series of 2,6-diiminopyridine-derived macrocyclic ligands have been synthesized via [2+2] condensation around alkaline earth metal triflate salts. The inclusion of a tert-butyl group at the 4-position of the pyridine ring of the macrocyclic synthons results in macrocyclic complexes that are solubl...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:Polyhedron
Hauptverfasser: Thierer, Laura M., Wang, Qiuran, Brooks, Sam H., Cui, Peng, Qi, Jia, Gau, Michael R., Manor, Brian C., Carroll, Patrick J., Tomson, Neil C.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2021
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7990114/
https://ncbi.nlm.nih.gov/pubmed/33776186
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2021.115044
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