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Unusual cyanide and methyl binding modes at a dicobalt macrocycle following acetonitrile C–C bond activation

This communication describes the C–C bond activation of acetonitrile and the trapping of the methyl and cyanide fragments by macrocyclic, dicobalt complexes. Both products display unique structural features as a result of the constraints imposed by the macrocycle. The bridged species [((3)PDI(2))Co(...

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Publicat a:Chem Commun (Camb)
Autors principals: Spentzos, Ariana Z., Gau, Michael R., Carroll, Patrick J., Tomson, Neil C.
Format: Artigo
Idioma:Inglês
Publicat: 2020
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7442599/
https://ncbi.nlm.nih.gov/pubmed/32696777
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc03521a
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